A
further life limiting factor is electrolyte water loss. VRLA batteries are designed
to operate during their entire service life without any topping-up
of the electrolyte with water. For this purpose, an oxygen recombination cycle
is introduced so to reduce the loss of electrolyte water to a minimum.
However water loss does nevertheless occur and has following magnitudes:
recombination efficiency < 100 % approx. 0.016 g per 100 Ah
cell
and day
excessive float current 0.336 g per ampere hour excessive
float current and cel
positive grid corrosion 0.17 g per gram of lead oxydized to
PbO
cell case transpiration approx. 0.06 g per 100 Ah cell and
day at +40 °C
self discharge reaction approx. 0.0336 g per 100 Ah cell and
day
at 20 °C
Excessive water loss by one or more of the above mechanisms can cause the
premature failure of a VRLA battery by a process called dry-out. Dry-out
results in reduced electrolyte volume and capacity loss.